Product ID:13538 ORANGE-YELLOW ZENTHANE PLUS MIL-PRF-85285C
MSDS Date:06/09/1999
FSC:8010
NIIN:01-441-6108
Status Code:A
MSDS Number: CLMYP

HENTZEN COATINGS INC

6937 WEST MILL ROAD
MILWAUKEE, WI 53218
US

Emergency Phone: 800-424-9300

Info Phone: 414-353-4200

Preparer: ERNEST CARTER

Cage: 09225

HENTZEN COATINGS INC

18749 MILWAUKEE, WI 53218 US

Telephone: 414-353-4200

Cage: 09225

HOMOPOLYMER OF HEXAMETHYLENE DIISOCYANATE

CAS: 28182-81-2

RTECS: NQ9170000

TITANIUM DIOXIDE

CAS: 13463-67-7

RTECS: XR2275000

OSHA PEL 15 MG/M3

ACGIH TLV: 10 MG/M3

METHYL PROPYL KETONE

CAS: 107-87-9

RTECS: SA7875000

OSHA PEL 700 MG/M3;200 PPM

ACGIH TLV: 705 MG/M3;200 PPM

HEXAMETHYLENE DIISOCYANATE

CAS: 822-06-0

RTECS: MO1740000

ACGIH TLV: 0.034 MG/M3;.005 PPM

EPA Report Quantity: 1 LB

DOT Report Quantity: 1 LB

1,2,4-TRIMETHYLBENZENE

CAS: 95-63-6

RTECS: DC3325000

AROMATIC HYDROCARBONS

CAS: 64742-95-6

RTECS: WF3400000

ANTIMONY, CHROME & NICKEL COMPOUND FOR SARA 313 REPORTING

METHOXYPROPANE ACETATE

CAS: 108-65-6

RTECS: AI8925000

METHYL AMYL KETONE

CAS: 110-43-0

RTECS: MJ5075000

OSHA PEL 465 MG/M3;100 PPM

ACGIH TLV: 233 MG/M3;50 PPM

Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:YES
Health Hazards Acute and Chronic:HARMFUL IF INHALED. MAY CAUSE THE
FOLLOWING EFFECTS: NOSE THROAT AND RESPIRATORY TRACT
IRRITATION.ALLERGIC RESPIRATORY REACTION. MAY CAUSE LUNG DAMAGE.
EYE AND SKIN IRRITATION. ALLERGIC SKIN REACTION. EYE CONTACT:
ACUTE EYE CONTACT WITH LIQUID, AEROSOLS AND VAPORS CAN BE
IRRITATING CAUSING TEARING, REDDENING AND SWELLING ACCOMPANIED BY A
STINGING AND/OR A FEELING LIKE OF FINE DUST IN THE EYES. SKI N
CONTACT: ISOCYANATES REACT WITH SKIN PROTEIN AND MOISTURE AND CAN
CAUSE IRRITATION. SYMPTOMS OF SKIN IRRITATION MAY BE REDDENING,
RASH, SWELLING, SCALING OR BLISTERING. INHALATION: ANESTHETIC. CAN
C AUSE IRRITATION OF THE RESPIRATORY .
Explanation of Carcinogenicity:THIS PRODUCT CONTAINS A TRIVALENT
CHROMIUM COMPOUND. IT IS NOT SPRCIFICALLY LISTED AS A CARCINOGEN BY
NTP, IARC OR ACGIH.
Effects of Overexposure:TRACT OR ACUTE NERVOUS SYSTEM DEPRESSION
CHARATERIZED BY THE FOLLOWING PROGRESSIVE STEPS IF SEVERE
OVEREXPOSURE IS CONTINUED: HEADACHE, DIZZINESS, STAGGERING GAIT,
CONFUSION OR UNCONSCIOUSNESS. INGEST ION: CAN RESULT IN IRRITATION
AND POSSIBLE CORROSIVE ACTION IN THE MOUTH, STOMACH TISSUE AND
DIGESTIVE TRACT. SYMPTOMS CAN INCLUDE SORE THROAT, ABDOMINAL PAIN,
NAUSEA, VOMITING AND DIARRHEA. VOMITIN G MAY CAUSE ASPIRATION OF
THE SOLVENT RESULTING IN CHEMICAL PNEUMONITIS.
Medical Cond Aggravated by Exposure:ASTHMA AND OTHER RESPIRATORY
AILMENTS; SKIN ALLERGIES AND ECZEMA; CHEMICAL SENSITIZATION.

First Aid:EYE CONTACT: FLUSH IMMEDIATELY WITH LOW PRESSURE LUKEWARM
RUNNING WATER FOR AT LEAST 15 MINUTES WHILE LIFTING EYELIDS. TAKE
TO A PHYSICIAN FOR TREATMENT.SKIN CONTACT: WASH AFFECTED AREAS
THOROUGHLY W ITH SOAP AND WATER.WASH CONTAMINATED CLOTHING
THOROUGHLY BEFORE REUSE. FOR SEVERE EXPOSURES, GET UNDER SAFETY
SHOWER AFTER REMOVING CLOTHING, THEN GET MEDICAL ATTENTION.
INHALATION: MOVE TO AN AREA F REE FROM RISK OF FURTHER
EXPOSURE.ADMINISTER OXYGEN OR ARTIFICIAL RESPIRATION AS NEEDED.
OBTAIN MEDICAL ATTENTION. INGESTION: CALL A PHYSICIAN
IMMEDIATELY. DO NOT INDUCE VOMITING

Flash Point Method:TCC
Flash Point:=7.8C, 46.F
Lower Limits:.90
Upper Limits:8.70
Extinguishing Media:CARBON DIOXIDE, DRY CHEMICAL, FOAM OR ALCOHOL FOAM.
Fire Fighting Procedures:FULL PROTECTIVE EQUIPMENT INCLUDING
SELF-CONTAINED BREATHING APPARATUS SHOULD BE WORN.DURING A FIRE,
IRRITATINGAND HIGHLY TOXIC GASES AND SMOKE ARE PRESENT FROM THE
DECOMPOSITION/COMBUSTION PRODUCTS. KEEP CONTAINERS TIGHTLY CLOSED.
ISOLATE FROM HEAT, ELECTRICAL EQUIPMENT, SPARKS AND OPEN FLAMES.

Spill Release Procedures:EVACUATE ALL NON-ESSENTIAL PERSONNEL AND
REMOVE ALL SOURCES OF IGNITION (FLAMES, HOT SURFACES, ELECTRICAL,
STATIC, FRICTION). VENTILATE AREA. PREVENT ENTRY INTO DRAINS. COVER
SPILL WITH INERT ABSORBEN T. POUR LIQUID DECONTAMINANT OVER
SPILLAGE, ALLOW TO REACT FOR TA LEAST 10 MINUTES. COLLECT MATERIAL
IN OPEN CONTAINERS AND ADD FURTHER AMOUNTS OF DECONTAMINATION
SOLUTION.

Handling and Storage Precautions:PRECAUTIONS MUST BE TAKEN SO THAT
PERSONS HANDLING THIS PRODUCT DO NOT BREATHE THE VPORS OR HAVE IT
CONTACT THE EYES OR SKIN.IN SPRAY OPERATIONS, PROTECTION.STORAGE:
DO NOT STORE ABOVE 120 F OR BELOW3 2 F. STORE LARGE QUANTITIES IN
BUILDINGS DESIGNED TO COMPLY WITH OSHA?S 29 CFR 1910.106. KEEP
CONTAI

Respiratory Protection:THE SURGEON GENERAL REQUIRES AIRLINE RESPIRATORS
TO BE USED UNLESS AIR SAMPLING SHOWS EXPOSURE TO BE BELOW OSHA
LIMITS. THEN, EITHER AIR-PURIFYING CHEMICAL CARTRIDGE RESPIRATORS
OR AIELINE RESPIRATORS ARE REQUIRED. THE SAME PRECAUTIONS SHOULD
BE USED DURING MIXING OR ANY OPERATIONS WHERE PAINT FUMES WOULD BE
PRESENT.
Ventilation:EXHAUST VENTILATION SUFFICIENT TO KEEP THE AIRBORNE
CONCENTRATIONS OF THE ISOCYANATES BELOW THEIR RESPECTIVE EXPOSURE
LIMITS MUST BE UTILIZED.
Protective Gloves:PERMEATION RESISTANT GLOVES.
Eye Protection:USE SAFETY EYEWEAR WITH SPLASH GUARDS OR SIDE SHIELDS.A
FULL FACE SHIELD
Other Protective Equipment:SAFETY SHOWERS AND EYE WASH STATIONS SHOULD
BE AVAILABLE. EDUCATE AND TRAIN EMPLOYEES IN THE SAFE USE OF THIS
PRODUCT.
Supplemental Safety and Health
MEDICAL SURVEILLANCE: PERSONS WITH ASTHMA-TYPE CONDITIONS, BRONCHITIS,
OTHER CHRONIC RESPIRATORY DISEASES OR RECURRENT SKIN ECZEMA OR
SENSITIZATION SHOULD BE EXCLUDED FROM WORKING WITH ISOCYANATES.

Boiling Pt:B.P. Text:LO-213.00-HI-418.00 F
Vapor Pres:27.800
Vapor Density:4.800
Spec Gravity:1.0900
VOC Pounds/Gallon:417
VOC Grams/Liter:3.48
Evaporation Rate & Reference:2.3000
Solubility in Water:REACTS WITH WATER
Appearance and Odor:OPQUE LIQUID SOLVENT ODOR
Percent Volatiles by Volume:49.224

Stability Indicator/Materials to Avoid:YES
CONTAMINATION WITH WATER, EPOXY CATALYSTS, ALCOHOLS, GLYCOL ETHERS,
BASES, METAL COMPLEXES OR OTHER ACTIVE MATERIALS. ONCE MATERIAL
EXPOSED TO ABOVE OR TO MOISTURE DO NOT RESEAL CONTAINER AS CARBON
DIOXIDE CAN BUILD UP.
Hazardous Decomposition Products:MAY PRODUCE HAZARDOUS FUMES WHEN
HEATED TO DECOMPOSITION AS IN WELDING: CARBON MONOXIDE, CARBON
DIOXIDE, CHLORINE, HYDROGEN CHLORIDE, CYANIDE, HEXAMETHYLENE
DIISOCYANATE.
Conditions to Avoid Polymerization:WILL NOT OCCUR.

Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH APPLICABLE LAWS
AND REGULATIONS.

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Disclaimer (provided with this information by the compiling agencies):
This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Transport Information:AS AN " ARTICLE" THIS PRODUCT IS EXCLUDED FROM
ANY REQUIREMENTS OF THE STANDARD. THIS IMPLIES THAT BATTERY MEETS
REQUIREMENTS OF REGULATIONS UNDER 49 CFR 173.159(D) AND REQUIRES
THAT BATTERIES BE PROT ECTED AGAINST SHORT CIRCUITS AND SECURELY
PACKAGED AND THE BATTERY AND OUTER PACKAGING PLAINLY AND DURABLY
MARKED "NONSPILLABLE" OR "NONSPILLABLE BATTERY". ALSO THE BATTERIES
MUST BE CAPABLE OF WITHST ANDING , WITHOUT LEAKAGE OF BATTERY
FLUID, THE VIBRATION TEST AND THE PRESSURE DIFFERENTIAL TEST
SPECIFIED IN 49 CFR 173.159(D)(3)(I) AND (I I).